Plasmonic Organic Solar Cells - Charge Generation and Recombination

von: Bo Wu, Nripan Mathews, Tze-Chien Sum

Springer-Verlag, 2016

ISBN: 9789811020216 , 114 Seiten

Format: PDF, OL

Kopierschutz: Wasserzeichen

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Plasmonic Organic Solar Cells - Charge Generation and Recombination


 

Contents

6

About the Authors

8

Abstract

10

1 Introduction

11

1.1 Organic Photovoltaics: Background

11

1.2 Materials: Conjugated Polymers

12

1.3 Operation Principles and Physical Insights in Organic Solar Cells (OSCs)

13

1.4 Organic Solar Cell Architectures

16

1.5 State-of-the-Art, Challenges and Opportunities in OSCs

19

1.6 Surface Plasmons for Improving Light Harvesting Efficiency

20

1.7 Other Contributions to Organic Photovoltaic Performance Improvement

25

1.8 State-of-the-Art and Challenges in Plasmonic Organic Solar Cells

26

References

27

2 Surface Plasmon Resonance

34

2.1 Introduction

34

2.2 Surface Plasmon Polariton

34

2.3 Localized Surface Plasmon Resonance

37

2.4 Summary

39

References

39

3 Characterization Plasmonic Organic Photovoltaic Devices

41

3.1 Introduction

41

3.2 Optical Spectroscopy

41

3.2.1 Steady-State and Transient Absorption Spectroscopies

41

3.2.2 Time-Integrated Photoluminescence and Time-Resolved Photoluminescence

45

3.2.3 Spatially Resolved Spectroscopy

47

3.3 Electrical Characterization

47

3.3.1 Current Voltage (I-V) Measurement

47

3.3.2 Internal Photon to Current Efficiency (IPCE) Measurement

48

3.4 Numerical Simulation

48

3.4.1 Optical Simulation

49

3.4.2 Electrical Simulation

50

3.5 Summary

53

References

54

4 Plasmonic Entities within the Charge Transporting Layer

55

4.1 Introduction

55

4.2 Case Study (1): Silver Nano-Triangle Arrays in PEDOT:PSS

57

4.3 Case Study (2): Gold Nanowire Network in PEDOT:PSS

66

4.4 Case Study (3): Single Silver Nanowire in PEDOT:PSS

75

4.5 Summary and Conclusions

84

References

84

5 Plasmonic Entities within the Active Layer

89

5.1 Introduction

89

5.2 Experimental Details

91

5.3 Results and Discussion

92

5.4 Summary and Conclusions

106

References

106

6 Concluding Remarks

109

6.1 Implications for the Design of Hybrid Plasmonic OPV Devices

109

6.2 Summary and Outlook

110

References

113