Organic Semiconductors in Sensor Applications

von: Daniel A. Bernards, Róisín M. Owens, George G. Malliaras

Springer-Verlag, 2008

ISBN: 9783540763147 , 290 Seiten

Format: PDF, OL

Kopierschutz: Wasserzeichen

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Organic Semiconductors in Sensor Applications


 

Preface

6

Contents

8

Contributors

13

1 Water Soluble Poly(.uorene) Homopolymers and Copolymers for Chemical and Biological Sensors

16

1.1 Introduction

16

1.2 General Structures and Properties

17

1.3 Signal Transduction Mechanisms in Sensors

24

1.4 Chemo- and Biosensor Applications

30

1.5 Heterogeneous Platforms

46

1.6 Summary and Outlook

47

References

49

2 Polyelectrolyte-Based Fluorescent Sensors

53

2.1 General Introduction

53

2.2 Enzyme Activity Assays

58

2.3 Conjugated Polyelectrolyte Surface-Grafted Colloids

68

2.4 Summary and Conclusions

71

References

72

3 Structurally Integrated Photoluminescent Chemical and Biological Sensors: An Organic Light-Emitting Diode-Based Platform

75

3.1 Introduction

75

3.2 Single Analyte Monitoring

78

3.3 Advanced Sensor Arrays

95

3.4 Future Directions

104

3.5 Summary and Concluding Remarks

106

References

106

4 Lab-on-a-Chip Devices with Organic Semiconductor-Based Optical Detection

111

4.1 Introduction

111

4.2 Fabrication

117

4.3 Functional Optical Components

130

4.4 Applications

140

4.5 Conclusions and Outlook

151

References

153

5 Solid-State Chemosensitive Organic Devices for Vapor-Phase Detection

155

5.1 Introduction

155

5.2 Survey of State-of-the-Art Vapor-Phase Solid-State Chemosensing Organic Devices

156

5.3 Recent Advances

174

References

194

6 Detection of Chemical and Physical Parameters by Means of Organic Field-Effect Transistors

199

6.1 Introduction

199

6.2 An Overview of Organic Field-E.ect Sensors

200

6.3 (Bio)chemosensing in Solution

202

6.4 Strain and Pressure Sensors

207

6.5 Design and Technology of Organic Field-Effect Sensors

216

6.6 Applications for Organic Field-Effect Sensors

219

6.7 Conclusions

224

References

224

7 Performance Requirements and Mechanistic Analysis of Organic Transistor-Based Phosphonate Gas Sensors

227

7.1 Overview of Electronic Sensors for Chemical Vapors and Warfare Agents

227

7.2 Organic Semiconductor Transistor Sensors

230

7.3 Testing Environments for Prototype Sensing Elements

233

7.4 Electrical Test Procedures

239

7.5 Responses of Functionalized Organic Semiconductors to DMMP

242

7.6 Data Analysis

248

7.7 Sensing Mechanisms and OFET Models

253

7.8 Summary and Outlook

256

References

257

8 Electrochemical Transistors for Applications in Chemical and Biological Sensing

259

8.1 Introduction

259

8.2 Sensors Based on Electrochemical Transistors

261

8.3 Recent advances in Design and Fabrication of Eletrochemical Transistors

272

8.4 Summary and Future Directions

274

References

275

9 PEDOT:PSS-Based Electrochemical Transistors for Ion-to-Electron Transduction and Sensor Signal Amplification

276

9.1 The PEDOT:PSS-Based Electrochemical Organic Thin Film Transistor

276

9.2 The PEDOT:PSS OECT as an Ion-to-Electron Transducer

282

9.3 The PEDOT:PSS Electrochemical transistor in logic and amplification circuits

285

9.4 Outlook

291

References

292

Index

294